Jolie and Pitt denied an on-set affair, but the rumors — and their combustible chemistry — made ‘Smith’ a $186M hit and likely contributed to Pitt’s January ’05 split from then-wife Jennifer Aniston. By spring, Brad and Angie were flaunting their romance in a W Magazine photo spread entitled “Domestic Bliss.” The rest is Brangelina history.

[AOL Moviefone]